ELECTROPOLYMERIZATION OF BENZENE IN A 2-PHASE STRONG PROTON ACID BENZENE SYSTEM

被引：4

作者：

GOLDENBERG, LM ^{[1
]}

AEIYACH, S ^{[1
]}

LACAZE, PC ^{[1
]}

机构：

[1] UNIV PARIS 07,ITODYS,CNRS,URA 34,1 RUE GUY DE LA BROSSE,F-75221 PARIS 05,FRANCE

来源：

SYNTHETIC METALS | 1992年 / 51卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(92)90289-U

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Anodic polymerization of benzene can be carried out under two-phase conditions if the electrode is immersed in the interfacial layer between benzene and acids of different strength, such as methanesulfonic, sulfuric, 20% fuming sulfuric, fluorosulfonic and trifluoromethanesulfonic acids. In all these cases the benzene oxidation is in the vicinity of 1 V/SCE. For films grown in usual acid media cyclic voltammetries are characterized by wide, ill-defined redox peaks. By contrast, in the superacids another state of the film with sharp redox peaks is observed. It is supposed that linear structure, with narrow distribution of the chain length, is realized in the latter case.

引用

页码：343 / 348

页数：6

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