REACTIVITY OF A SILANEDIYL TOWARDS NITRILES - THE ROLE OF AZASILACYCLOPROPENES AS INTERMEDIATES

被引:17
作者
BELZNER, J [1 ]
IHMELS, H [1 ]
NOLTEMEYER, M [1 ]
机构
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY
关键词
D O I
10.1016/0040-4039(95)01749-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Cyclotrisilane la reacts with different nitriles to yield products 4-6, the formation of which is likely to proceed via initially generated azasilacylopropenes 3a-c. Disilane 6 represents the first example of a structurally characterized pentacoordinated silyl cyanide.
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页码:8187 / 8190
页数:4
相关论文
共 13 条
[1]  
BAGOTT JE, 1987, CHEM PHYS LETT, V135, P39
[2]   THE DISORDERED STRUCTURE OF TRIMETHYLSILY1 CYANIDE AT 140-K WHICH GIVES SHARP AND DIFFUSE-X-RAY REFLECTIONS [J].
BARROW, MJ .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (JAN) :150-154
[3]   REACTIONS OF A CYCLOTRISILANE WITH OLEFINS AND DIENES - EVIDENCE FOR AN EQUILIBRIUM BETWEEN SILYLENES AND A CYCLOTRISILANE [J].
BELZNER, J ;
IHMELS, H ;
KNEISEL, BO ;
GOULD, RO ;
HERBSTIRMER, R .
ORGANOMETALLICS, 1995, 14 (01) :305-311
[4]   REACTIONS OF A CYCLOTRISILANE WITH ALKYNES - SYNTHESIS AND FIRST CRYSTAL-STRUCTURE OF 1,2-DISILACYCLOBUT-3-ENES [J].
BELZNER, J ;
IHMELS, H ;
KNEISEL, BO ;
HERBSTIRMER, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (17) :1989-1990
[5]  
BELZNER J, 1993, TETRAHEDRON LETT, P6541
[6]  
CORRIU RJP, 1989, CHEM ORGANIC SILICON, P1241
[7]  
OLSON L, 1995, J AM CHEM SOC, V117, P7460
[8]   PHOSPHASILIRENES, 3-MEMBERED RINGS CONTAINING PC DOUBLE-BONDS [J].
SCHAFER, A ;
WEIDENBRUCH, M ;
SAAK, W ;
POHL, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (08) :776-777
[9]  
SCHAFER A, 1987, ANGEW CHEM, V99, P806
[10]   SILICON-COMPOUNDS WITH STRONG INTRAMOLECULAR STERIC INTERACTIONS .48. TRISILACYCLOBUTANIMINES - MOLECULAR-STRUCTURES AND PHOTOINDUCED REACTIONS [J].
WEIDENBRUCH, M ;
HAMANN, J ;
PETERS, K ;
VONSCHNERING, HG ;
MARSMANN, H .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 441 (02) :185-195