PHOTOCHEMISTRY OF ANTHRACENE IN WATER

被引：47

作者：

SIGMAN, ME ^{[1
]}

ZINGG, SP ^{[1
]}

PAGNI, RM ^{[1
]}

BURNS, JH ^{[1
]}

机构：

[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 41期

关键词：

ANTHRACENE; PHOTOCHEMISTRY; PHOTOOXIDATION; WATER;

D O I：

10.1016/S0040-4039(00)93543-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photolysis of anthracene (350 nm) in aerated water yields endoperoxide and 9,10-anthraquinone as the major primary photoproducts. Photolysis of anthracene in oxygen-deficient aqueous solutions yields the three isomers of 10,10'-dihydroxy-9,9',10,10'-tetrahydro-9,9'-bianthryl as the primary photoproduct. Involvement of a cation radical mechanism is suggested.

引用

收藏

页码：5737 / 5740

页数：4

相关论文

共 16 条

[1] THE SYMMETRICAL DIANTHRYLS .1. [J].

BELL, F ;

WARING, DH .

JOURNAL OF THE CHEMICAL SOCIETY, 1949, (FEB) :267-269

[2]

BJORSETH A, 1986, PAH WORK ATMOSPHERES, P35

[3] DETERMINATION OF WAVELENGTH-AVERAGED, NEAR UV QUANTUM YIELDS FOR ENVIRONMENTAL CHEMICALS [J].

DRAPER, WM .

CHEMOSPHERE, 1985, 14 (09) :1195-1203

[4] THERMAL-DECOMPOSITION OF PEROXYDISULFATE IN AQUEOUS-SOLUTIONS OF BENZENE NITROBENZENE BENZONITRILE MIXTURES - FORMATION OF OH RADICALS FROM BENZENE RADICAL CATIONS AND WATER AT ROOM-TEMPERATURE [J].

EBERHARDT, MK ;

MARTINEZ, GA ;

RIVERA, JI ;

FUENTESAPONTE, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (25) :7069-7073

[5]

HERCULES DM, 1984, ANAL CHEM, V46, P674

[6] CONTROLLED POTENTIAL OXIDATION OF ANTHRACENE IN ACETONITRILE .2. [J].

MAJESKI, EJ ;

STUART, JD ;

OHNESORG, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (03) :633-+

[7] PHOTOLYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS IN WATER [J].

MILL, T ;

MABEY, WR ;

LAN, BY ;

BARAZE, A .

CHEMOSPHERE, 1981, 10 (11-1) :1281-1290

[8] SYN-ANTHRACENE 4A,10-9,9A-DIOXIDE [J].

RIGAUDY, J ;

DEFOIN, A ;

BARANNELAFONT, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (05) :413-415

[9] WAVELENGTH-DEPENDENT AND DUAL PHOTOCHEMISTRY OF THE ENDOPEROXIDES OF ANTHRACENE AND 9,10-DIMETHYLANTHRACENE [J].

SCHMIDT, R ;

SCHAFFNER, K ;

TROST, W ;

BRAUER, HD .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (05) :956-958

[10] PHOTOOXIDATION OF ANTHRACENE [J].

SUGIYAMA, N ;

IWATA, M ;

YOSHIOKA, M ;

YAMADA, K ;

AOYAMA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1969, 42 (05) :1377-+