INFLUENCE OF CHELATING GROUPS ON THE LUMINESCENCE PROPERTIES OF EUROPIUM(III) AND TERBIUM(III) CHELATES IN THE 2,2'-BIPYRIDINE SERIES

被引：57

作者：

MUKKALA, VM

KWIATKOWSKI, M

KANKARE, J

TAKALO, H

机构：

[1] UNIV TURKU,DEPT CHEM,SF-20500 TURKU 50,FINLAND

[2] CTR BIOTECHNOL,SF-20521 TURKU,FINLAND

来源：

HELVETICA CHIMICA ACTA | 1993年 / 76卷 / 02期

关键词：

D O I：

10.1002/hlca.19930760213

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Eight different 2,2'-bipyridine derivatives, i.e. 2, 5, 8, 10, 12, 13, 15, and 19 (Schemes 1 and 2), were prepared to study the influence of the chelating groups on the luminescence properties of their Eu(III) and Tb(III) chelates. According to our luminescence results, 2,2'-(methylenenitrilo)bis(acetic acid) as well as (methylenenitrilo)bis(methylphosphonic acid) in 6- and 6'-position of 2,2'-bipyridine is a suitable group when developing luminescent markers for bioaffinity assays based on time-resolved luminescence measurement.

引用

页码：893 / 899

页数：7

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