DOUBLE-HELICAL DINUCLEAR COPPER(I) COMPLEXES OF MACROCYCLIC BIS(DITHIADIIMINE) LIGANDS

被引：34

作者：

COMBA, P

FATH, A

HAMBLEY, TW

RICHENS, DT

机构：

[1] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA

[2] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 17期

关键词：

COMPLEXES WITH MACROCYCLIC LIGANDS; COPPER COMPOUNDS; HELICAL STRUCTURES; MOLECULAR MODELING; SUPRAMOLECULAR CHEMISTRY;

D O I：

10.1002/anie.199518831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

32‐ and 34‐membered macrocyclic Schiff base type ligands with (N2S2)2 donor units are synthesized in a high‐yielding [2 + 2] condensation reaction. Coordination of these ligands to copper(I) results in double helical dicopper(I) complexes with a new figure‐of‐eight loop structure (see diagram on the right). (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1883 / 1885

页数：3

共 33 条

[1] HELICAL GROUP-12 COORDINATION - THE X-RAY CRYSTAL-STRUCTURE OF A 5-CO-ORDINATE ZINC(II) COMPLEX [J].