BRONSTED ACID-CATALYZED ELECTROPHILIC SUBSTITUTION OF INDOLE BY ALLYLIC ALCOHOLS IN LITHIUM PERCHLORATE DIETHYL-ETHER - APPLICATION TO THE TOTAL SYNTHESIS OF YUEHCHUKENE

被引：41

作者：

HENRY, KJ ^{[1
]}

GRIECO, PA ^{[1
]}

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 06期

关键词：

D O I：

10.1039/c39930000510

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel carbon-carbon bond-forming reaction between indole and beta,beta-disubstituted allylic alcohols in lithium perchlorate-diethyl ether containing a catalytic amount of a Bronsted acid is described; the reaction has been applied to a total synthesis of yuehchukene.

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页码：510 / 512

页数：3

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