ENZYME CATALYZED MONOHYDROLYSIS OF 2-ARYL-1,3-PROPANEDIOL DIACETATES - A STUDY OF STRUCTURAL EFFECTS OF THE ARYL MOIETY ON THE ENANTIOSELECTIVITY

被引：59

作者：

GUANTI, G

NARISANO, E

PODGORSKI, T

THEA, S

WILLIAMS, A

机构：

[1] CNR,CTR STUDIO DIARILOIDI,I-16132 GENOA,ITALY

[2] UNIV KENT,CHEM LABS,CANTERBURY CT2 7NH,KENT,ENGLAND

来源：

TETRAHEDRON | 1990年 / 46卷 / 20期

关键词：

D O I：

10.1016/S0040-4020(01)87892-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

PPL catalyzed monohydrolysis of 2-aryl substituted 13-propanediol diacetates afforded the corresponding monoacetates in acceptable to fair chemical and optical yields. Electronic effects in the aromatic ring were examined. Elaboration of some 2-arylpropanediol monoacetates to optically active 2-arylpropanols and propanoic acids was performed. © 1990.

引用

页码：7081 / 7092

页数：12

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