ENZYME CATALYZED MONOHYDROLYSIS OF 2-ARYL-1,3-PROPANEDIOL DIACETATES - A STUDY OF STRUCTURAL EFFECTS OF THE ARYL MOIETY ON THE ENANTIOSELECTIVITY

被引：59

作者：

GUANTI, G

NARISANO, E

PODGORSKI, T

THEA, S

WILLIAMS, A

机构：

[1] CNR,CTR STUDIO DIARILOIDI,I-16132 GENOA,ITALY

[2] UNIV KENT,CHEM LABS,CANTERBURY CT2 7NH,KENT,ENGLAND

来源：

TETRAHEDRON | 1990年 / 46卷 / 20期

关键词：

D O I：

10.1016/S0040-4020(01)87892-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

PPL catalyzed monohydrolysis of 2-aryl substituted 13-propanediol diacetates afforded the corresponding monoacetates in acceptable to fair chemical and optical yields. Electronic effects in the aromatic ring were examined. Elaboration of some 2-arylpropanediol monoacetates to optically active 2-arylpropanols and propanoic acids was performed. © 1990.

引用

页码：7081 / 7092

页数：12

共 40 条

[31] PERSPECTIVES IN NONSTEROIDAL ANTIINFLAMMATORY AGENTS
SHEN, TY
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1972, 11 (06) : 460 - &
[32] STAUB H, 1942, HELV CHIM ACTA, V15, P649
[33] RAPID CHROMATOGRAPHIC TECHNIQUE FOR PREPARATIVE SEPARATIONS WITH MODERATE RESOLUTION
STILL, WC
KAHN, M
MITRA, A
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (14) : 2923 - 2925
[34] SUNJIC V, 1989, GAZZ CHIM ITAL, V119, P229
[35] REDUCTIVE PINACOL-TYPE REARRANGEMENT OF CHIRAL ALPHA-MESYLOXY KETONES PROMOTED BY ORGANO-ALUMINUM COMPOUNDS
SUZUKI, K
KATAYAMA, E
MATSUMOTO, T
TSUCHIHASHI, G
[J]. TETRAHEDRON LETTERS, 1984, 25 (34) : 3715 - 3718
[36] TABER DF, 1985, J AM CHEM SOC, V107, P196, DOI 10.1021/ja00287a035
[37] ENANTIODIVERGENT ROUTE TO THE AROMATIC BISABOLANE SESQUITERPENES BY REGIO-CONTROLLED AND STEREO-CONTROLLED EPOXIDE OPENING
TAKANO, S
YANASE, M
SUGIHARA, T
OGASAWARA, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (23) : 1538 - 1540
[38] SYNTHESIS OF BOTH ENANTIOMERIC FORMS OF 2-SUBSTITUTED 1,3-PROPANEDIOL MONOACETATES STARTING FROM A COMMON PROCHIRAL PRECURSOR, USING ENZYMATIC TRANSFORMATIONS IN AQUEOUS AND IN ORGANIC MEDIA
TOMBO, GMR
SCHAR, HP
FERNANDEZ, X
BUSQUETS, I
GHISALBA, O
[J]. TETRAHEDRON LETTERS, 1986, 27 (47) : 5707 - 5710
[39] BIFUNCTIONAL CHIRAL SYNTHONS VIA BIOCHEMICAL METHODS .4. CHIRAL PRECURSORS TO (+)-BIOTIN AND (-)-A-FACTOR
WANG, YF
SIH, CJ
[J]. TETRAHEDRON LETTERS, 1984, 25 (44) : 4999 - 5002
[40] DISIC ACIDS - STUDY OF A NEW SERIES OF STRONG ORGANIC-ACIDS AND THEIR CONDENSATION PRODUCTS WITH ALDEHYDES
ZVILICHOVSKY, G
[J]. TETRAHEDRON, 1975, 31 (16) : 1861 - 1867

← 1 2 3 4 →