UNUSUAL INTRAMOLECULAR HYDROGEN-BONDING IN CY2GABRNH2PH - THE 1ST STRUCTURALLY CHARACTERIZED DIALKYL GALLIUM HALIDE PRIMARY AMINE ADDUCT

被引：12

作者：

ATWOOD, DA ^{[1
]}

COWLEY, AH ^{[1
]}

JONES, RA ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 430卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(92)86012-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The aniline adduct of dicyclohexyl gallium bromide Cy2GaBrNH2Ph (1) provides the first example of a structurally characterized dialkyl gallium halide primary amine adduct. X-ray crystallographic data indicate the possibility of an intramolecular hydrogen bond between the bromide and a hydrogen of the amine group (H...Br = 2.48 angstrom).

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页码：C29 / C32

页数：4

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