TRANSITION-METAL ENOLATE CHEMISTRY - FORMATION OF A PALLADIUM ALKYL COMPLEX FROM A HIGHLY REACTIVE ENOLATOPALLADIUM COMPLEX

被引：26

作者：

BALEGROUNE, F

GRANDJEAN, D

LAKKIS, D

MATT, D

机构：

[1] ECOLE EUROPEENNE HAUTES ETUD IND CHIM STRASBOURG,CHIM INORGAN LAB,CNRS,URA 416,F-67008 STRASBOURG,FRANCE

[2] UNIV RENNES 1,CRISTALLOCHIM LAB,CNRS,URA 1495,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 15期

关键词：

D O I：

10.1039/c39920001084

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ester-derived palladium enolate [LPd{Ph2PCH = C(O)OEt}] 1 (L = o-C6H4CH2NMe2) reacts instantly with dimethyl acetylenedicarboxylate and tetracyanoethylene in tetrahydrofuran (THF) to yield respectively the alkenyl complex [LPd{Ph2PCH[C(O)OEt](MeO2CC = CCO2Me)}] 2 and the alkyl complex [LPd{Ph2PCH[C(O)OEt][(NC)2CC(CN2)]}] 3.

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页码：1084 / 1085

页数：2

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