A NEW SYNTHESIS OF SUBSTITUTED DIENES BY REDUCTIVE ELIMINATION OF ALLYLIC NITRO-DERIVATIVES

被引：11

作者：

BARLAAM, B ^{[1
]}

BOIVIN, J ^{[1
]}

ZARD, SZ ^{[1
]}

机构：

[1] ECOLE POLYTECH,SYNTHESE ORGAN LAB,CNRS,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 06期

关键词：

ALLYLIC NITRO COMPOUNDS; REDUCTION; DIENES; CHROMOUS ACETATE;

D O I：

10.1016/S0040-4039(00)77482-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tertiary allylic nitro compounds. bearing an acetate or a mesylate in beta position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetatel 2,2'-dipyridyl in DMF at 110-120-degrees-C.

引用

页码：1023 / 1026

页数：4

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