A NEW SYNTHESIS OF SUBSTITUTED DIENES BY REDUCTIVE ELIMINATION OF ALLYLIC NITRO-DERIVATIVES

被引：11

作者：

BARLAAM, B ^{[1
]}

BOIVIN, J ^{[1
]}

ZARD, SZ ^{[1
]}

机构：

[1] ECOLE POLYTECH,SYNTHESE ORGAN LAB,CNRS,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 06期

关键词：

ALLYLIC NITRO COMPOUNDS; REDUCTION; DIENES; CHROMOUS ACETATE;

D O I：

10.1016/S0040-4039(00)77482-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tertiary allylic nitro compounds. bearing an acetate or a mesylate in beta position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetatel 2,2'-dipyridyl in DMF at 110-120-degrees-C.

引用

页码：1023 / 1026

页数：4

共 26 条

[21] REDUCTION OF AROMATIC AND ALIPHATIC NITRO-COMPOUNDS BY SODIUM HYDROGEN TELLURIDE [J].

OSUKA, A ;

SHIMIZU, H ;

SUZUKI, H .

CHEMISTRY LETTERS, 1983, (09) :1373-1374

[22] CONTROLLED POTENTIAL ELECTROLYSIS .13. POLAROGRAPHIC BEHAVIOUR AND CONTROLLED POTENTIAL ELECTROLYSES IN ACETONITRILE OF SEVERAL ALIPHATIC TERTIARY NITRO COMPOUNDS [J].

SAYO, H ;

TSUKITAN.Y ;

MASUI, M .

TETRAHEDRON, 1968, 24 (04) :1717-&

[23]

SEEBACH D, 1979, CHIMIA, V33, P1

[24]

TAMURA R, 1991, SYNTHESIS-STUTTGART, P423

[25] FACILE SYNTHESIS OF ALLYLIC NITROCOMPOUNDS BY N,N-DIMETHYLETHYLENEDIAMINE-CATALYZED CONDENSATION OF ALIPHATIC AND ALICYCLIC KETONES WITH PRIMARY NITROALKANES [J].

TAMURA, R ;

SATO, M ;

ODA, D .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (23) :4368-4375

[26] CHROMIUM(II) CHLORIDE REDUCTION OF BETA-ARYL, ALPHA,BETA-UNSATURATED NITROALKENES - A FACILE ROUTE TO OXIMES [J].

VARMA, RS ;

VARMA, M ;

KABALKA, GW .

SYNTHETIC COMMUNICATIONS, 1985, 15 (14) :1325-1332

← 1 2 3 →