CONTROLLED OXIDATION OF ENOLATES TO ALPHA-CARBONYL RADICALS AND ALPHA-CARBONYL CATIONS

被引：43

作者：

ROCK, M ^{[1
]}

SCHMITTEL, M ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ORGAN CHEM & BIOCHEM,ALBERTSTR 21,D-79104 FREIBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 23期

关键词：

D O I：

10.1039/c39930001739

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Depending on the oxidation strength of the one-electron oxidants either persistent alpha-carbonyl radicals or a-carbonyl cation derived benzofurans are formed from enolates A1-A6, a result which can readily be rationalized by the measured oxidation potentials of enolates A1-A6 and alpha-carbonyl radicals R1-R6.

引用

页码：1739 / 1741

页数：3

共 35 条

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