THE STRUCTURE OF A NOVEL CEMBRANOID DITERPENE FROM A PHILIPPINE COLLECTION OF THE SOFT CORAL SINULARIA-FLEXIBILIS

被引:22
作者
GUERRERO, PP
READ, RW
BATLEY, M
JANAIRO, GC
机构
[1] UNIV NEW S WALES,SCH CHEM,SYDNEY,NSW 2052,AUSTRALIA
[2] MACQUARIE UNIV,SCH CHEM,N RYDE,NSW 2109,AUSTRALIA
[3] DE LA SALLE UNIV,DEPT CHEM,MANILA,PHILIPPINES
来源
JOURNAL OF NATURAL PRODUCTS-LLOYDIA | 1995年 / 58卷 / 08期
关键词
D O I
10.1021/np50122a005
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
A new optically active diterpene lactone, sinulariolone [1], has been isolated as the major secondary metabolite in a Philippine collection of Sinularia flexibilis. The compound has a tricyclic structure and is more highly oxygenated than previously reported diterpenes from this species. The structure of 1 was elucidated by spectroscopy and its relative stereochemistry confirmed by single-crystal X-ray crystallography.
引用
收藏
页码:1185 / 1191
页数:7
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