ENHANCED ENANTIOSELECTIVITY OF THE LIPASE-CATALYZED HYDROLYSIS BY THE ADDITION OF A CATALYTIC AMOUNT OF AN AMINO ALCOHOL

被引:33
作者
ITOH, T [1 ]
OHIRA, E [1 ]
TAKAGI, Y [1 ]
NISHIYAMA, S [1 ]
NAKAMURA, K [1 ]
机构
[1] KYOTO UNIV, INST CENT RES, UJI, KYOTO 611, JAPAN
关键词
D O I
10.1246/bcsj.64.624
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
L-Methioninol (L-MetOH) was discovered to be an effective additive for improving the enantioselectivity of lipase-catalyzed hydrolysis. It was found that L-MetOH accelerated the enzyme-catalyzed hydrolysis of (R)-3-acetoxybutyronitrile (1) and inhibited that of (S)-1.
引用
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页码:624 / 627
页数:4
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