A NEW METHOD FOR THE SYNTHESIS OF IRON AZADIENE AND DIENE COMPLEXES - REACTION OF (ETA-2-RCHCHCOR')FE(CO)4 WITH ANILINE AND YLIDE

被引：22

作者：

SEMMELHACK, MF ^{[1
]}

CHENG, CH ^{[1
]}

机构：

[1] TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 393卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(90)80203-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of (η2-RCHCHCOR′)Fe(CO)4 (R = Ph, R′ = H; R = H, R′ = H and R = H, R′ = CH3) with aniline or its derivative afforded η4-azadiene complexes 1, 2 and 3 in various yields. The azadiene ligands in 2 and 3 are too reactive to isolate at ambient temperature, but 2 and 3 are stable up to ca 110 ° C. Treatment of (η2-CH2CHCHO)Fe(CO)4 with Ph3PCHCOOMe gave a η2-diene complex 4 which was converted to (η4-CH2CHCHCHCOOMe)Fe(CO)3 on heating, or reacting with (CH3)3NO. © 1990.

引用

页码：237 / 241

页数：5