RUTHENIUM COMPLEX-CATALYZED ADDITION OF N-ARYL SUBSTITUTED AMIDES TO ALKYNES - NOVEL SYNTHESIS OF ENAMIDES

被引:84
作者
KONDO, T [1 ]
TANAKA, A [1 ]
KOTACHI, S [1 ]
WATANABE, Y [1 ]
机构
[1] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN
关键词
D O I
10.1039/c39950000413
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The addition of N-aryl substituted amides to non-activated terminal alkynes is efficiently promoted by the Ru-3(CO)(12)-PCy(3) catalyst system, affording the corresponding linear (E)-enamides in good yields with high regio- and stereo-selectivity.
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页码:413 / 414
页数:2
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