RUTHENIUM COMPLEX-CATALYZED ADDITION OF N-ARYL SUBSTITUTED AMIDES TO ALKYNES - NOVEL SYNTHESIS OF ENAMIDES

被引：84

作者：

KONDO, T ^{[1
]}

TANAKA, A ^{[1
]}

KOTACHI, S ^{[1
]}

WATANABE, Y ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 04期

关键词：

D O I：

10.1039/c39950000413

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of N-aryl substituted amides to non-activated terminal alkynes is efficiently promoted by the Ru-3(CO)(12)-PCy(3) catalyst system, affording the corresponding linear (E)-enamides in good yields with high regio- and stereo-selectivity.

引用

页码：413 / 414

页数：2

共 13 条

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[12] A NEW SYNTHESIS OF 2-ALKYL AND 2-ACYL KETONES
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[13] DODECACARBONYLTRIRUTHENIUM CATALYZED ONE-TO-ONE ADDITION OF N-SUBSTITUTED FORMAMIDES TO OLEFINS
TSUJI, Y
YOSHII, S
OHSUMI, T
KONDO, T
WATANABE, Y
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 331 (03) : 379 - 385

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