PREPARATION OF HOMOCHIRAL CROWN-ETHER CONTAINING (S)-1-(1-ADAMANTYL)ETHANE-1,2-DIOL AS A CHIRAL SUBUNIT AND ITS ENANTIOSELECTIVE COMPLEXATION WITH AN ORGANIC AMMONIUM CATION

被引：17

作者：

NAEMURA, K ^{[1
]}

MIZOOKU, T ^{[1
]}

KAMADA, K ^{[1
]}

HIROSE, K ^{[1
]}

TOBE, Y ^{[1
]}

SAWADA, M ^{[1
]}

TAKAI, Y ^{[1
]}

机构：

[1] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 08期

关键词：

D O I：

10.1016/0957-4166(94)80125-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homochiral 1-(1-adamantyl)ethane-1,2-diol(5) was prepared and its absolute configuration was determined to be (S)-(+)-5 by enzymatic and H-1 n.m.r. spectroscopic methods. Using (S)-(+)-5 as a chiral subunit, the homochiral crown ether (+)-18 was synthesized and its enantioselectivity in complexation of methionine methyl ester perchlorate was also examined by the H-1 n.m.r. spectroscopic method.

引用

页码：1549 / 1558

页数：10

共 11 条

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