DYNAMIC NUCLEAR MAGNETIC-RESONANCE STUDY OF GROUP-6 METAL PENTACARBONYL COMPLEXES - PYRAMIDAL INVERSION AND 1,2-METAL SHIFTS IN THE COMPLEXES [M(CO)5(ME2CCH2EECH2)] (M = CR, MO, OR W - E = S OR SE)

被引：22

作者：

ABEL, EW ^{[1
]}

MITTAL, PK ^{[1
]}

ORRELL, KG ^{[1
]}

SIK, V ^{[1
]}

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1985年 / 08期

关键词：

D O I：

10.1039/dt9850001569

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1569 / 1575

页数：7

共 32 条

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[5] PYRAMIDAL INVERSIONS AND 1,2-METAL SHIFTS IN PENTACARBONYL-CHROMIUM, PENTACARBONYL-MOLYBDENUM, AND PENTACARBONYL-TUNGSTEN DERIVATIVES OF DIALKYL DISULFIDES AND DIALKYL DISELENIDES - A NUCLEAR MAGNETIC-RESONANCE INVESTIGATION
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[8] NUCLEAR MAGNETIC-RESONANCE INVESTIGATIONS OF CONFIGURATIONAL NONRIGIDITY IN DINUCLEAR PLATINUM(IV) COMPLEXES .4. RING REVERSAL, PYRAMIDAL INVERSION, AND NOVEL FLUXIONAL REARRANGEMENTS IN [(PTXME3)2-(MESCH2SEME)] COMPLEXES
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[10] RING REVERSAL, SULFUR INVERSION, AND 1,3-METAL SHIFTS IN SULFUR-CONTAINING SIX-MEMBERED-RING COMPLEXES OF CHROMIUM AND TUNGSTEN CARBONYLS
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