CHROMIUM DIRECTED REGIOCONTROL AND STEREOCONTROL - A NEW CHAPTER IN AROMATIC NATURAL PRODUCT SYNTHESIS

被引：42

作者：

DICKENS, PJ

GILDAY, JP

NEGRI, JT

WIDDOWSON, DA

机构：

[1] Department of Chemistry, Imperial College, Londor

来源：

PURE AND APPLIED CHEMISTRY | 1990年 / 62卷 / 04期

关键词：

D O I：

10.1351/pac199062040575

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sequence of ortho-directing abilities of a series of aryl functionalities in arenetricarbonylchromium(O) complexes has been shown to be different to that in the uncomplexed arenes. The kinetic resolution of the lithiated complexes with homochiral oxazolidinones has been rationalised via a transition state model and applied to the stereocontrolled synthesis of a series of highly functionalised, homochiral phenethylamines. © 1990, IUPAC.

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页码：575 / 581

页数：7

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