SILAHETEROCYCLES .10. NOVEL NAPHTHALENE-SILENE AND CYCLOHEXA-1,3-DIENE-SILENE CYCLOADDUCTS

被引：24

作者：

AUNER, N

SEIDENSCHWARZ, C

HERDTWECK, E

SEWALD, N

机构：

[1] Anorganisch-Chemisches Institut, Technischen Universität München, Garching, W-8046

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 04期

关键词：

D O I：

10.1002/anie.199104441

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

''Dichloroneopentylsilaethene'' 1 reacts with naphthalene in a surprising [4 + 2] cycloaddition to give the endo product 2. This can be reduced with LiAlH4 to afford 3, which was analyzed by X-ray crystallography. A reaction of 1 with cyclohexa-1,3-diene forms bicyclic silacyclobutanes in a [2 + 2] cycloaddition.

引用

页码：444 / 446

页数：3

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