ELECTROCHEMISTRY OF ZEOLITE-ENCAPSULATED COMPLEXES .3. CHARACTERIZATION OF IRON AND MANGANESE SALEN ENTRAPPED IN Y-FAUJASITE TYPE ZEOLITE

被引：61

作者：

GAILLON, L

SAJOT, N

BEDIOUI, F

DEVYNCK, J

BALKUS, KJ

机构：

[1] ECOLE NATL SUPER CHIM,ELECTROCHIM LAB,CNRS,URA 216,11 RUE PIERRE & MARIE CURIE,F-75231 PARIS 05,FRANCE

[2] UNIV TEXAS,DEPT CHEM,RICHARDSON,TX 75083

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 345卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-0728(93)80476-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

[Mn(III)SALEN]+ and [Fe(III)SALEN]+ complexes have been entrapped in the supercages of zeolite Y. The redox properties of these zeolite-encapsulated complexes are investigated by cyclic voltammetry in acetonitrile and dimethyl sulphoxide solutions. The results show the existence of two kinds of entrapped [Fe(III)SALEN]+ forms within the zeolite. Their existence is related to the mechanism of their preparation and depends on the electrolytic media. The electroactivity of encapsulated Mn-SALEN towards the biomimetic activation of molecular oxygen is discussed.

引用

页码：157 / 167

页数：11

共 23 条

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