CARBONYLATION OF DIAMINO-LIGATED METHYLPALLADIUM(II) METHOXIDE COMPLEXES

被引：10

作者：

KAPTEIJN, GM ^{[1
]}

VERHOEF, MJ ^{[1
]}

VANDENBROEK, MAFH ^{[1
]}

GROVE, DM ^{[1
]}

VANKOTEN, G ^{[1
]}

机构：

[1] UNIV UTRECHT,DEBYE RES INST,DEPT MET MEDIATED SYNTH,3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 503卷 / 01期

关键词：

PALLADIUM; METHOXYCARBONYL COMPLEXES; ACYL; CARBONYLATION; METHOXIDE; PERFLUOROALKOXIDE;

D O I：

10.1016/0022-328X(95)05694-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The methylpalladium(II) methoxide complexes [Pd(Me)(OMe)(N similar to N)] (N similar to N = tmeda or bpy) have been synthesized by alkoxide-methanol exchange of [Pd(Me)(OCH(CF3)(2))(N similar to N)] in MeOH. The bpy complex undergoes insertion of CO to give either a methyl(methoxycarbonyl) complex [Pd(Me)(CO(2)Me)(bpy)](at -60 degrees C) or an acyl(methoxycarbonyl) complex [Pd(COMe)(CO(2)Me)(bpy)] (at -25 degrees C). Both carbonylated species were isolated and characterized at low temperature.

引用

页码：C26 / C28

页数：3

共 15 条

[1]

ALSTERS PL, 1992, ORGANOMETALLICS, V11, P4214

[2] STEREOCHEMISTRY OF OXIDATIVE ADDITION OF BENZYL-ALPHA-D CHLORIDE AND BROMIDE TO "TRIS(TRIETHYLPHOSPHINE)PALLADIUM(0) - DIRECT OBSERVATION OF OPTICAL-ACTIVITY IN A CARBON-PALLADIUM SIGM-BONDED COMPLEX [J].

BECKER, Y ;

STILLE, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (03) :838-844

[3] MONOMERIC METAL-HYDROXIDES, ALKOXIDES, AND AMIDES OF THE LATE TRANSITION-METALS - SYNTHESIS, REACTIONS, AND THERMOCHEMISTRY [J].

BRYNDZA, HE ;

TAM, W .

CHEMICAL REVIEWS, 1988, 88 (07) :1163-1188

[4] EFFICIENT PALLADIUM CATALYSTS FOR THE CARBONYLATION OF ALKYNES [J].

DRENT, E ;

ARNOLDY, P ;

BUDZELAAR, PHM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 455 (1-2) :247-253

[5]

DRENT E, 1990, J ORGANOMET CHEM, V417, P235

[6]

KAPTEIJN GM, 1993, INORG CHIM ACTA, V207, P131

[7]

KAPTEIJN GM, 1995, UNPUB J AM CHEM SOC

[8] ALKYLNICKEL AND ALKLPALLADIUM ALKOXIDES ASSOCIATED WITH ALCOHOLS THROUGH HYDROGEN-BONDING [J].

KIM, YJ ;

OSAKADA, K ;

TAKENAKA, A ;

YAMAMOTO, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (03) :1096-1104

[9] PREPARATION AND PROPERTIES OF NEW METHYL(ALKOXO)NICKEL AND METHYL(THIOLATO)NICKEL AND METHYL(ALKOXO)PALLADIUM AND METHYL(THIOLATO)PALLADIUM COMPLEXES - CO AND CS2 INSERTION INTO THE ALKOXO PALLADIUM BOND [J].

KIM, YJ ;

OSAKADA, K ;

SUGITA, K ;

YAMAMOTO, T ;

YAMAMOTO, A .

ORGANOMETALLICS, 1988, 7 (10) :2182-2188

[10] REDUCTIVE ELIMINATION OF ARYL CARBOXYLATES FROM ACYL(ARYLOXY)NICKEL(II) AND ACYL(ARYLOXY)PALLADIUM(II) COMPLEXES [J].

KOMIYA, S ;

AKAI, Y ;

TANAKA, K ;

YAMAMOTO, T ;

YAMAMOTO, A .

ORGANOMETALLICS, 1985, 4 (06) :1130-1136

← 1 2 →