CARBONYLATION OF DIAMINO-LIGATED METHYLPALLADIUM(II) METHOXIDE COMPLEXES

被引：10

作者：

KAPTEIJN, GM ^{[1
]}

VERHOEF, MJ ^{[1
]}

VANDENBROEK, MAFH ^{[1
]}

GROVE, DM ^{[1
]}

VANKOTEN, G ^{[1
]}

机构：

[1] UNIV UTRECHT,DEBYE RES INST,DEPT MET MEDIATED SYNTH,3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 503卷 / 01期

关键词：

PALLADIUM; METHOXYCARBONYL COMPLEXES; ACYL; CARBONYLATION; METHOXIDE; PERFLUOROALKOXIDE;

D O I：

10.1016/0022-328X(95)05694-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The methylpalladium(II) methoxide complexes [Pd(Me)(OMe)(N similar to N)] (N similar to N = tmeda or bpy) have been synthesized by alkoxide-methanol exchange of [Pd(Me)(OCH(CF3)(2))(N similar to N)] in MeOH. The bpy complex undergoes insertion of CO to give either a methyl(methoxycarbonyl) complex [Pd(Me)(CO(2)Me)(bpy)](at -60 degrees C) or an acyl(methoxycarbonyl) complex [Pd(COMe)(CO(2)Me)(bpy)] (at -25 degrees C). Both carbonylated species were isolated and characterized at low temperature.

引用

页码：C26 / C28

页数：3

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