HIGHLY DIASTEREOSELECTIVE ALDOL REACTIONS OF 4-THIANONE - A NEW STRATEGY FOR SYNTHESIS OF POLYPROPIONATE FRAMES

被引：25

作者：

HAYASHI, T

机构：

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 39期

关键词：

4-THIANONE; ALDOL REACTION; DIASTEREOSELECTIVITY; THREO-SELECTIVITY; DIASTEROFACE SELECTIVITY;

D O I：

10.1016/S0040-4039(00)92388-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aldol reactions of the lithium enolate of 4-thianone with aldehydes yield the threo-isomers of aldols in a highly stereoselective manner and also showed high diastereoface selectivity. Other metal enolates of this reagent exhibited different behabiors from those of the corresponding cyclohexane enolates.

引用

页码：5369 / 5372

页数：4

共 34 条

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