NOVEL TEMPERATURE DEPENDENCES OF HELICAL PITCH IN FERROELECTRIC AND ANTIFERROELECTRIC CHIRAL SMECTIC LIQUID-CRYSTALS

A variety of temperature dependences of helical pitch were found in ferroelectric SmC* and antiferroelectric SmC(A)* chiral smectic liquid crystals with large spontaneous polarization. In the vicinity of the transition temperatures of the materials showing the second-order SmA-SmC* or SmA-SmC(A)* phase transition, the pitch gradually increases with decreasing temperature over several degrees. In the materials which show the first-order phase transition from SmA to SmC* or to SmC(A)*, the maximum pitch suddenly appears at the transition. It was also confirmed in all of the materials used that the helix undergoes a discontinuous change in the pitch length and its handedness at the SmC*-SmC(A)* phase transition. The molecular orientational structure of the ferrielectric phase is also discussed on the basis of the temperature dependence of the pitch of (S)-MHPOBC.