STUDIES OF THE POLYMER-METAL INTERFACE IN METAL-PPV-METAL DEVICES

被引：29

作者：

NGUYEN, TP ^{[1
]}

MASSARDIER, V ^{[1
]}

TRAN, VH ^{[1
]}

GUYOT, A ^{[1
]}

机构：

[1] LAB MAT ORGAN,F-69390 VERNAISON,FRANCE

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 01期

关键词：

D O I：

10.1016/0379-6779(93)90939-T

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We report the results obtained from electrical measurements and surface analysis by photoelectron spectroscopy (XPS) performed in polyparaphenylene-vinylene (PPV) thin films sandwiched between metallic electrodes. Current-voltage characteristics of metal-polymer-metal devices are dissymetrical with rectifying contacts at top electrodes (Cr or Al) and blocking one at bottom electrodes (Cr). Analysis of the core level spectra of carbon, oxygen and metals in the interfacial layers leads to the conclusion that the rectifying behaviour of polymer-metal contact is in close relation with the formation of metallic oxide-carbon complexes at the interfaces.

引用

页码：235 / 240

页数：6