PHOSPHETANES AS CHIRAL LIGANDS FOR CATALYTIC ASYMMETRIC REACTIONS - HYDROSILYLATION OF OLEFINS

被引：41

作者：

MARINETTI, A

RICARD, L

机构：

[1] Laboratoire “Hétéroéléments et Coordination”, URA CNRS 1499,DCPH, Ecole Poly technique, Cedex

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 10期

关键词：

D O I：

10.1021/om00022a035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple methodology has been developed for the synthesis of P-menthylphosphetanes having known stereochemistry at several chiral centers, including phosphorus. These new electron-rich chiral phosphines have been tested as ligands in olefin hydrogenation reactions and in the palladium-catalyzed hydrosilylation of styrene and cyclopentadiene. High activity and significant enantiomeric excesses have been obtained when using a 1:1 phosphine/Cl2-Pd(PhCN)2 mixture as the catalyst. Within each set of epimeric phosphetanes, the enantiomeric excesses are highly dependent on the relative configurations of the sequence of chiral centers.

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页码：3956 / 3962

页数：7

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