HUND CASE (E) - APPLICATION TO RYDBERG STATES WITH A 2-PI IONIC CORE

被引：39

作者：

LEFEBVREBRION, H

机构：

[1] Laboratoire de Photophysique Moléculaire, Bâtiment 213, Université de Paris-Sud

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 93卷 / 08期

关键词：

D O I：

10.1063/1.459499

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Rydberg states of high n belonging to series converging to an ion state with a nonzero spin-orbit splitting must be described in so-called Hund's case (e). The derivation of the wave function obtained by transition from case (a) to case (e) is given. Application is made for a 2Π ionic core. This scheme is particularly useful to understand, for example, rotationally resolved spin-orbit autoionization. © 1990 American Institute of Physics.

引用

页码：5898 / 5901

页数：4