SYNTHESIS AND REACTIVITY OF (TRICARBONYL)-(ETA-5-2-METHYLPENTADIENYL)IRON(+ 1) CATION

被引：28

作者：

DONALDSON, WA

机构：

[1] Department of Chemistry, Marquette University, Milwaukee

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 395卷 / 02期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/0022-328X(90)85276-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The (tricarbonyl)(η5-2-methylpentadienyl)iron(+1) cation was prepared by the protonation of (tricarbonyl)(4-methyl-2,4-pentadienol)iron. Reaction of the cation with H2O, allyl-TMS, NaBH3CN, PPh3, malonate and 3-furyl cuprate gave (η4-1,3-diene)Fe(CO)3 complexes. The regioselectivity for the nucleophilic attack appears to be sterically controlled. © 1990.

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页码：187 / 193

页数：7

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