COPPER-SENSITIVE MODIFIED POLY(PYRROLE) ELECTRODE

被引：14

作者：

ARCA, M ^{[1
]}

YILDIZ, A ^{[1
]}

机构：

[1] HACETTEPE UNIV,DEPT CHEM,ANKARA 06532,TURKEY

来源：

ELECTROANALYSIS | 1994年 / 6卷 / 01期

关键词：

COPPER; POLY(PYRROLE); MODIFIED ELECTRODE;

D O I：

10.1002/elan.1140060115

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A copper ion sensitive poly(pyrrole) electrode, containing diethyldithio-carbamate as a ligand is described. The ligand was incorporated into the electrochemically-prepared polymer coating via anion exchange. Cyclic voltammetry and infrared spectroscopy were used to characterize the modified electrode surface. The uptake of copper ions was achieved by electroreduction at -0.65 V (vs. SCE), and the cyclic-voltametric anodic peak current of the complex ion at +0.55 V (vs. Ag/AgCl) was used for analysis. A detection limit for copper ions was estimated to be 1 ppm.

引用

页码：79 / 82

页数：4

共 19 条

[1]

ARCA M, 1988, RADIAT PHYS CHEM, V31, P647

[2] THE ELECTRODEPOSITION OF POLY-N-METHYLPYRROLE FILMS FROM AQUEOUS-SOLUTIONS [J].