METATHESIS OF OMEGA-UNSATURATED GLUCOSIDES WITH CHLORO-ARYLOXIDE COMPLEXES OF TUNGSTEN, AS A NEW WAY LEADING TO UNSATURATED BOLAAMPHIPHILES

被引:27
作者
DESCOTES, G [1 ]
RAMZA, J [1 ]
BASSET, JM [1 ]
PAGANO, S [1 ]
机构
[1] CNRS,CHIM ORGANOMET SURFACE LAB,F-69626 VILLEURBANNE,FRANCE
关键词
D O I
10.1016/0040-4039(94)85319-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Glucosides of unsaturated alcohols, bearing different protecting soups at glucose units underwent catalytic metathesis affording bolaamphiphiles with good yields. Tungsten aryloxo-complexes (1 and 2) were found to be superior catalysts for this process.
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页码:7379 / 7382
页数:4
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