METATHESIS OF OMEGA-UNSATURATED GLUCOSIDES WITH CHLORO-ARYLOXIDE COMPLEXES OF TUNGSTEN, AS A NEW WAY LEADING TO UNSATURATED BOLAAMPHIPHILES

被引：27

作者：

DESCOTES, G ^{[1
]}

RAMZA, J ^{[1
]}

BASSET, JM ^{[1
]}

PAGANO, S ^{[1
]}

机构：

[1] CNRS,CHIM ORGANOMET SURFACE LAB,F-69626 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 40期

关键词：

D O I：

10.1016/0040-4039(94)85319-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Glucosides of unsaturated alcohols, bearing different protecting soups at glucose units underwent catalytic metathesis affording bolaamphiphiles with good yields. Tungsten aryloxo-complexes (1 and 2) were found to be superior catalysts for this process.

引用

页码：7379 / 7382

页数：4

共 15 条

[11] Ivin K J., 1983, OLEFIN METATHESIS
[12] METATHESIS OF FUNCTIONALIZED ACYCLIC OLEFINS
MOL, JC
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1991, 65 (1-2): : 145 - 162
[13] ULTRATHIN MONOLAYER LIPID-MEMBRANES FROM A NEW FAMILY OF CROWN ETHER-BASED BOLA-AMPHIPHILES
MUNOZ, S
MALLEN, J
NAKANO, A
CHEN, ZH
GAY, I
ECHEGOYEN, L
GOKEL, GW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (05) : 1705 - 1711
[14] ARYLOXIDE LIGANDS IN METATHESIS OF OLEFINS AND OLEFINIC ESTERS - CATALYTIC BEHAVIOR OF W(OAR)2CL4 COMPLEXES ASSOCIATED WITH ALKYL-TIN OR ALKYL-LEAD COCATALYSTS - ALKYLATION OF W(OAR)2CL4 BY SNME4, SN(N-BU)4, PB(N-BU)4, MGNP2 - SYNTHESIS OF W(OAR)2CL2(CHCME3)(OR2) AND W(OAR)2CL(CHCME3)(CH2CME3)(OR2)
QUIGNARD, F
LECONTE, M
BASSET, JM
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1986, 36 (1-2): : 13 - 29
[15] ARYLOXIDE LIGANDS IN THE METATHESIS OF OLEFINS - SYNTHESES OF W(OAR)XCL6-X COMPLEXES WITH X = 2, 3, AND 4 - CRYSTAL-STRUCTURES OF W(O-2,6-C6H3-I-PR2)3CL3 AND W(O-2,6-C6H3PH2)2CL4
QUIGNARD, F
LECONTE, M
BASSET, JM
HSU, LY
ALEXANDER, JJ
SHORE, SG
[J]. INORGANIC CHEMISTRY, 1987, 26 (25) : 4272 - 4277

← 1 2 →