SYNTHETIC STUDIES OF SESQUITERPENES WITH A CIS-FUSED DECALIN SYSTEM .6. ISOLATION, STRUCTURE ELUCIDATION, AND SYNTHESIS OF NORSESQUIBENIHIOL AND THE SYNTHESIS OF DEHYDROCHAMAECYNENOL

被引：4

作者：

ANDO, M ^{[1
]}

KIKUCHI, K ^{[1
]}

ISOGAI, K ^{[1
]}

IBE, S ^{[1
]}

ASAO, T ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF NATURAL PRODUCTS-LLOYDIA | 1995年 / 58卷 / 02期

关键词：

D O I：

10.1021/np50116a003

中图分类号：

Q94 [植物学];

学科分类号：

071001 [植物学];

摘要：

Norsesquibenihol, a new norsesquiterpene alcohol, was isolated from the essential oil of Chamaecyparis formosensis and its structure was elucidated as 8 by spectroscopic methods. Allylic rearrangement of the 3 beta- and 3 alpha-alcohols 18 and 19, which were derived from the known acetylenic ketone 9 in three steps, gave a mixture of 8 and dehydrochamaecynenol [6]. The structure of norsesquibenihiol [8] was therefore proved by this synthesis.

引用

页码：177 / 183

页数：7

共 10 条

[1]

SYNTHETIC STUDIES OF SESQUITERPENES WITH A CIS-FUSED DECALIN SYSTEM .5. A SYNTHETIC APPROACH TO THE STUDY OF STRUCTURE-ACTIVITY-RELATIONSHIPS OF THE TERMITICIDAL NORSESQUITERPENOIDS, CHAMAECYNONE AND RELATED-COMPOUNDS [J].