KINETIC AND STRUCTURAL STUDY, USING REAL-TIME NEUTRON-DIFFRACTION, ON THE INSERTION OF TETRAHYDROFURANS IN KC24 AND RBC24

被引：10

作者：

MARCUS, B ^{[1
]}

TOUZAIN, P ^{[1
]}

HAMWI, A ^{[1
]}

机构：

[1] UNIV CLERMONT FERRAND 2,CHEM SOLIDES LAB,CNRS,ERA 897,F-63170 AUBIERE,FRANCE

来源：

CARBON | 1986年 / 24卷 / 04期

关键词：

POTASSIUM COMPOUNDS - RUBIDIUM COMPOUNDS;

D O I：

10.1016/0008-6223(86)90259-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of tetrahydrofuran (THF) with KC//2//4 and RbC//2//4 graphite intercalation compounds has been studied in situ by neutron diffraction measurements. The patterns obtained during intercalation and deintercalation of the organic molecules were recorded on a time scale of two minutes/spectrum using a DIB multidetector. The THF action leads to first stage ternary compounds via intermediary second stage ternary phases.

引用

页码：403 / 410

页数：8

共 24 条

[11]

HEROLD A, 1955, B SOC CHIM, P995

[12] TERNARY LAMELLAR GRAPHITE COMPOUNDS WITH POTASSIUM AND METHYLBENZENES [J].

ISAEV, YV ;

NOVIKOV, YN ;

VOLPIN, ME ;

RASHKOV, I ;

PANAYOTOV, I .

SYNTHETIC METALS, 1983, 6 (01) :9-14

[13] ELECTRON-DIFFRACTION FROM SUPER-LATTICES IN GRAPHITE-RUBIDIUM INTERCALATION COMPOUNDS [J].

KAMBE, N ;

DRESSELHAUS, G ;

DRESSELHAUS, MS .

PHYSICAL REVIEW B, 1980, 21 (08) :3491-3501

[14] THE EFFECT OF INTERCALATION ON THE LATTICE-CONSTANTS OF GRAPHITE [J].

KRAPCHEV, T ;

OGILVIE, R ;

DRESSELHAUS, MS .

CARBON, 1982, 20 (04) :331-337

[15] STRUCTURAL STUDIES OF GRAPHITE-INTERCALATION COMPOUNDS USING (00L) X-RAY-DIFFRACTION [J].

LEUNG, SY ;

DRESSELHAUS, MS ;

UNDERHILL, C ;

KRAPCHEV, T ;

DRESSELHAUS, G ;

WUENSCH, BJ .

PHYSICAL REVIEW B, 1981, 24 (06) :3505-3518

[16] TWIST CONFORMATION OF TETRAHYDROFURAN IN THE CRYSTAL [J].

LUGER, P ;

BUSCHMANN, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (05) :410-410

[17] SCANNING-TRANSMISSION ELECTRON-MICROSCOPY OF MULTIPHASES IN GRAPHITE ALKALI-METAL INTERCALATION COMPOUNDS [J].

MAZUREK, H ;

DRESSELHAUS, MS ;

DRESSELHAUS, G .

CARBON, 1982, 20 (04) :297-301

[18] X-RAY-DIFFRACTION STUDY ON BENZENE PENETRATION IN KC24 [J].

MERLE, G ;

MAI, C ;

GOLE, J ;

RASHKOV, I .

CARBON, 1977, 15 (04) :243-245

[19] ANALYTICAL AND STRUCTURAL STUDY OF TERNARY GRAPHITE-ALKALI METAL-TETRAHYDROFURAN INTERCALATION PRODUCTS [J].

NOMINE, M ;

BONNETAI.L .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1969, 66 (10) :1731-&

[20] STRUCTURE OF TERNARY INTERCALATION COMPOUNDS OBTAINED FROM KC24 UNDER THE ACTION OF DIMETHOXYETHANE IN THE PRESENCE OF ELECTRON-ACCEPTORS [J].

RASHKOV, I ;

SHISHKOVA, V ;

PANAYOTOV, I ;

MERLE, G ;

LETOFFE, JM .

MATERIALS SCIENCE AND ENGINEERING, 1983, 57 (02) :155-159

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