LARGE AND STABLE NONLINEAR-OPTICAL EFFECTS OBSERVED FOR A POLYIMIDE COVALENTLY INCORPORATING A NONLINEAR-OPTICAL CHROMOPHORE

被引：115

作者：

BECKER, MW

SAPOCHAK, LS

GHOSEN, R

XU, CZ

DALTON, LR

SHI, YQ

STEIER, WH

JEN, AKY

机构：

[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089

[2] UNIV SO CALIF,DEPT ELECT ENGN,LOS ANGELES,CA 90089

[3] ENICHEM AMER INC,MOMMOUTH JUNCT,NJ 08852

来源：

CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 02期

关键词：

D O I：

10.1021/cm00038a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A high-T(g) polyimide has been synthesized for nonlinear optical studies- The polyamic acid precursor polymer can be efficiently poled and imidized yielding a d33 coefficient of 2.8 x 10(-7) esu. Exceptional dynamic thermal stability was observed up to 185-degrees-C and temporal stability of the nonlinear optical signal at 90-degrees-C is realized for hundreds of hours with insignificant loss of optical activity.

引用

页码：104 / 106

页数：3