NOE CORRELATIONS IN MTPA, MNCB AND MBNC ESTERS

被引：21

作者：

FUKUSHI, Y

YAJIMA, C

MIZUTANI, J

机构：

[1] Department of Applied Bioscience, Faculty of Agriculture, Hokkaido University, Kita-ku, Sapporo

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)78558-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

NOEs are observed between the protons of the acid moieties and the protons of the alcohol moieties in some alpha-methoxy-alpha-trifluoromethylphenylacetic acid (MTPA, 1), 2-(2'-methoxy-1'naphthyl)-3-5,dichlorobenzoic acid (MNCB, 2), and 2'-methoxy-1,1'-binaphthyl-2-carboxylic acid (MBNC, 3) esters. This initial observation could be another clue to determine the absolute configurations of chiral alcohols.

引用

页码：9417 / 9420

页数：4

共 6 条

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