TITANIUM (IV) CATALYSIS IN THE REDUCTION OF PHOSPHINE OXIDES

被引：145

作者：

COUMBE, T ^{[1
]}

LAWRENCE, NJ ^{[1
]}

MUHAMMAD, F ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)75855-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phosphine oxides can be reduced by triethoxysilane, or more conveniently polymethylhydrosiloxane, and catalytic titanium (IV) isopropoxide and provides a system for the efficient one-pot generation of phosphonium salts; the reduction occurs with retention of configuration at phosphorus.

引用

页码：625 / 628

页数：4

共 17 条

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