ASYMMETRIC TOTAL SYNTHESIS OF AN A-RING PRECURSOR TO HORMONALLY ACTIVE 1-ALPHA,25-DIHYDROXYVITAMIN-D3

被引：78

作者：

POSNER, GH

KINTER, CM

机构：

[1] Department of Chemistry, The Johns Hopkins University, Baltimore

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 13期

关键词：

D O I：

10.1021/jo00300a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: A new sulfinyl orthoester has been designed and used effectively in one-flask syntheses of dienoate esters from allylic alcohols; this new method as well as a highly stereocontrolled [2 + 4]-cycloaddition are applied to synthesis of lα,25-dihydroxyvitamin D3. © 1990, American Chemical Society. All rights reserved.

引用

页码：3967 / 3969

页数：3

共 72 条

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