HIGHLY EFFICIENT PALLADIUM CATALYST SYSTEM FOR INSERTION OF ACETYLENES INTO SI-SI BONDS - A NEW METHOD FOR MODIFICATION OF SILICON-CONTAINING POLYMERS

被引：91

作者：

YAMASHITA, H

CATELLANI, M

TANAKA, M

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 02期

关键词：

D O I：

10.1246/cl.1991.241

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Pd(dba)2-2P(OCH2)3CEt (dba = dibenzylideneacetone) system exhibited highly efficient catalysis in the insertion of acetylenes into Si-Si bonds of hexamethyldisilane, octamethyltrisilane, poly[(disilanylene)phenylene], poly[(disilanylene)-ethylene], and poly(dimethylsilylene).

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页码：241 / 244

页数：4

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