SYNTHESIS AND STRUCTURES OF STERICALLY CROWDED ARYLOXIDE-SUBSTITUTED ALUMINUM-CHLORIDE

被引：22

作者：

SCHULZ, S ^{[1
]}

ROESKY, HW ^{[1
]}

NOLTEMEYER, M ^{[1
]}

SCHMIDT, HG ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 02期

关键词：

D O I：

10.1039/dt9950000177

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of AlCl3 with Li(OR').Et(2)O (R' = C(6)H(2)Bu(3)(t)-2.4,6) in diethyl ether gave AI(OR')Cl-2.Et(2)0 1, a monomeric aryloxide compound of aluminium. Its reaction with 2 equivalents of potassium gave elemental aluminium and [Al(OEt)(OR')(2)](2) 2 containing a four-membered Al2O2 ring. Compound 1 crystallizes in the monoclinic space group P2(1)/c with a = 10.692(2). b = 21.825(4), c = 11.683(2) Angstrom and beta=115.49(3)degrees and compound 2 in the space group P $($) over bar$$ 1 with a = 10.227(2). b = 10.966(2), c = 18.493(4) Angstrom, alpha = 101.13(3). beta = 97.63(3) and gamma = 115.29(3)degrees.

引用

页码：177 / 180

页数：4

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