ADSORPTION OF CESIUM ON MINERALS - A REVIEW

被引:368
作者
CORNELL, RM
机构
[1] Laboratorium für anorganische Chemie, ETH Zürich, Zürich
来源
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1993年 / 171卷 / 02期
关键词
D O I
10.1007/BF02219872
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The adsorption behavior of cesium on pure minerals is reviewed. Although this field has been investigated intensively, the data arc extremely variable in scope and interpretation with detailed information being available for only a few minerals. In current investigations in this field, the emphasis is on the nature of the adsorption sites and identification of these sites using spectroscopic techniques. In the first section of this review, the general mechanism of cesium adsorption is discussed and this is followed by consideration of the effect of parameters such as cesium concentration, the properties of the mineral and the characteristics of the solution phase, on cesium adsorption. Finally, interaction of cesium with some different minerals is described in some detail.
引用
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页码:483 / 500
页数:18
相关论文
共 66 条
[11]  
COLEMAN N. T., 1965, SOIL SCI, V99, P243, DOI 10.1097/00010694-196504000-00006
[12]  
COLEMAN N. T., 1963, SOIL SCI SOC AMER PROC, V27, P287
[13]  
COMANS RNJ, 1991, GEOCHIM COSMOCHIM AC, V55, P433
[14]   QUANTITATIVE-ANALYSIS OF RADIOCESIUM RETENTION IN SOILS [J].
CREMERS, A ;
ELSEN, A ;
DEPRETER, P ;
MAES, A .
NATURE, 1988, 335 (6187) :247-249
[15]   CATION EXCHANGE SELECTIVITY OF SOME CLAY-SIZED MINERALS AND SOIL MATERIALS [J].
DOLCATER, DL ;
LOTSE, EG ;
SYERS, JK ;
JACKSON, ML .
SOIL SCIENCE SOCIETY OF AMERICA PROCEEDINGS, 1968, 32 (06) :795-+
[16]  
ERTEN HN, 1988, RADIOCHIM ACTA, V44-5, P147
[17]   REVERSIBLE ION-EXCHANGE FIXATION OF CESIUM-137 LEADING TO MOBILIZATION FROM RESERVOIR SEDIMENTS [J].
EVANS, DW ;
ALBERTS, JJ ;
CLARK, RA .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1983, 47 (06) :1041-1049
[18]   PREFERENTIAL ADSORPTION OF CS-137 TO MICACEOUS MINERALS IN CONTAMINATED FRESHWATER SEDIMENT [J].
FRANCIS, CW ;
BRINKLEY, FS .
NATURE, 1976, 260 (5551) :511-513
[19]   CESIUM DISTRIBUTION COEFFICIENTS IN UNCONSOLIDATED GEOLOGICAL-MATERIALS [J].
GILLHAM, RW ;
CHERRY, JA ;
LINDSAY, LE .
HEALTH PHYSICS, 1980, 39 (04) :637-649
[20]  
GILLHAM RW, 1978, PNLSA7352