A CLASSIFICATION SCHEME FOR HOMOGENEOUS METAL-CATALYZED OXIDATIONS BY O-2

被引：19

作者：

DRAGO, RS

BEER, RH

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

INORGANICA CHIMICA ACTA | 1992年 / 198卷

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0020-1693(00)92378-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The metal complex catalyzed oxidation of organic substrates is an important area of chemistry with relevance to biological and industrial processes. The immense literature in the area can be overwhelming with considerable speculation concerning the role metals play in the process. In this article, the reactions metal complexes undergo in the activation of O2 are divided into five classes. The classification serves as a guide for the selection of metal complexes to catalyze the oxidation of organic substrates. It also provides a summary of established reaction types for an investigator to consider before proposing a new mechanism.

引用

页码：359 / 367

页数：9

共 94 条

[81]

SHELDON RA, 1973, RECL TRAV CHIM PAY B, V92, P253

[82] SYNTHETIC AND MECHANISTIC ASPECTS OF METAL-CATALYZED EPOXIDATIONS WITH HYDROPEROXIDES [J].