SYNTHESIS OF NEW CHIRAL ARENE RUTHENIUM(II) AMINOPHOSPHINEPHOSPHINITE COMPLEXES AND USE IN ASYMMETRIC HYDROGENATION OF AN ACTIVATED KETO COMPOUND

被引：26

作者：

HAPIOT, F ^{[1
]}

AGBOSSOU, F ^{[1
]}

MORTREUX, A ^{[1
]}

机构：

[1] UNIV SCI & TECH LILLE FLANDRES ARTOIS,CATALYSE HETEROGENE & HOMOGENE LAB,CNRS,URA 402,F-59652 VILLENEUVE DASCQ,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 04期

关键词：

D O I：

10.1016/0957-4166(94)80006-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The easy access to new arene ruthenium(II)bisphosphine complexes bearing aminophosphine phosphinite ligands is presented. The complexes were prepared in two steps from [RuX(2)(arene)](2) under mild conditions and were found to be effective precursors for the asymmetric hydrogenation of dihydro-4,4-dimethyl-2,3-furandione giving the corresponding pantolactone with up to 42% enantiomeric excess.

引用

页码：515 / 518

页数：4

共 50 条

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