SYNTHESIS, STRUCTURE, AND DYNAMIC BEHAVIOR OF A NEW SERIES OF TITANACYCLOPENTANE COMPOUNDS CONTAINING ANCILLARY ARYLOXIDE LIGANDS

被引:30
作者
HILL, JE [1 ]
FANWICK, PE [1 ]
ROTHWELL, IP [1 ]
机构
[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907
关键词
MOLECULAR-STRUCTURE; TRANSITION-METALS; CARBON CARBON; COMPLEXES; CHEMISTRY; TITANIUM; CYCLIZATION; REACTIVITY; GROUP-4; OLEFINS;
D O I
10.1021/om00047a009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new series of titanacyclopentane compounds have been isolated by reaction of the titanacyclopentadiene complex [Ti(OAr")2(C4Et4)] (OAr" = 2,6-diphenylphenoxide) with ethylene, propene, and 1-butene.
引用
收藏
页码:15 / 16
页数:2
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