SYNTHESIS, STRUCTURE, AND DYNAMIC BEHAVIOR OF A NEW SERIES OF TITANACYCLOPENTANE COMPOUNDS CONTAINING ANCILLARY ARYLOXIDE LIGANDS

被引：30

作者：

HILL, JE ^{[1
]}

FANWICK, PE ^{[1
]}

ROTHWELL, IP ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 01期

关键词：

MOLECULAR-STRUCTURE; TRANSITION-METALS; CARBON CARBON; COMPLEXES; CHEMISTRY; TITANIUM; CYCLIZATION; REACTIVITY; GROUP-4; OLEFINS;

D O I：

10.1021/om00047a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new series of titanacyclopentane compounds have been isolated by reaction of the titanacyclopentadiene complex [Ti(OAr")2(C4Et4)] (OAr" = 2,6-diphenylphenoxide) with ethylene, propene, and 1-butene.

引用

页码：15 / 16

页数：2

共 45 条

[21]

GRUBBS RH, 1982, COMPREHENSIVE ORGANO

[22] ISOLATION AND CHARACTERIZATION OF TI(O)(OAR-2,6PRI2)2(NC5H4-4NC4H8)2(OAR-2,6PRI2=2,6-DIISOPROPYLPHENOXIDE - NC5H4-4NC4H8=4-PYRROLIDINOPYRIDINE) - A MONONUCLEAR ARYLOXIDE COMPOUND CONTAINING A TERMINAL TITANIUM(IV)-OXO GROUP [J].

HILL, JE ;

FANWICK, PE ;

ROTHWELL, IP .

INORGANIC CHEMISTRY, 1989, 28 (18) :3602-3604

[23] FORMATION, FRAGMENTATION, AND ISOMERIZATION OF TITANACYCLE RINGS SUPPORTED BY ARYLOXIDE LIGATION [J].

HILL, JE ;

FANWICK, PE ;

ROTHWELL, IP .

ORGANOMETALLICS, 1990, 9 (08) :2211-2213

[24]

INGROSSO G, 1986, REACTIONS COORDINATE, V1, P639

[25]

KAI Y, 1982, CHEM LETT, P1979, DOI 10.1246/cl.1982.1979

[26] SYNTHESIS AND STRUCTURE OF A TUNGSTACYCLOPENTATRIENE [J].

KERSCHNER, JL ;

FANWICK, PE ;

ROTHWELL, IP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (24) :8235-8238

[27] A FORMAL 4 + 1 ROUTE TO ALKYLIDENE CYCLOPENTENEDIONES - A SYNTHETIC APPLICATION OF THE TRANSITION-METAL-CATALYZED TERMINAL ALKYNE REVERSIBLE VINYLIDENE REARRANGEMENT [J].

LIEBESKIND, LS ;

CHIDAMBARAM, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (16) :5025-5026

[28]

MANRIQUEZ JM, 1978, J AM CHEM SOC, V100, P716

[29] SYNTHESIS AND REACTIONS OF BIS(CYCLOPENTADIENYL)TITANIUM(IV) METALLOCYCLES [J].

MCDERMOTT, JX ;

WILSON, ME ;

WHITESIDES, GM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (21) :6529-6536

[30] ZIEGLER-NATTA CATALYSIS - AN ALTERNATIVE MECHANISM INVOLVING METALLACYCLES [J].

MCKINNEY, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (11) :490-492

← 1 2 3 4 5 →