POLAR/PI INTERACTIONS BETWEEN STACKED ARYLS IN 1,8-DIARYLNAPHTHALENES

被引：316

作者：

COZZI, F ^{[1
]}

CINQUINI, M ^{[1
]}

ANNUNZIATA, R ^{[1
]}

DWYER, T ^{[1
]}

SIEGEL, JS ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM,LA JOLLA,CA 92093

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 14期

关键词：

D O I：

10.1021/ja00040a036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of substituted 1,8-diarylnaphthalenes, II-X, has been prepared, and the barrier to rotation about the aryl-naphthalene bond has been measured. A monotonic increasing relationship between DELTA-G(double dagger) and sigma(para) values has been found. This is interpreted in terms of a through-space polar interaction between the two aryl units.

引用

页码：5729 / 5733

页数：5

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