DETERMINATION OF ALPHA-ZEARALENOL AND BETA-ZEARALENOL AND ZEARALENONE IN CEREALS BY GAS-CHROMATOGRAPHY WITH ION-TRAP DETECTION

被引：24

作者：

SCHWADORF, K ^{[1
]}

MULLER, HM ^{[1
]}

机构：

[1] UNIV HOHENHEIM,INST ANIM NUTR,EMIL WOLFF STR 10,W-7000 STUTTGART 70,GERMANY

来源：

JOURNAL OF CHROMATOGRAPHY | 1992年 / 595卷 / 1-2期

关键词：

D O I：

10.1016/0021-9673(92)85168-S

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method for determination of the estrogenic mycotoxins, alpha- and beta-zearalenol and zearalenone. in cereals (wheat, barley, oats, corn) is described. After extraction with ethylacetate, clean-up involved a base treatment and partition with water, derivatization was by trimethylsilylation. For quantitation and confirmation a capillary gas chromatograph combined with a selective mass detector (ion trap), working in the electron impact-mode was used. The detection limit for the complete method is 1-mu-g/kg for each of the three mycotoxins in full scan. Recoveries from spiked cereals were 82- 86%.

引用

页码：259 / 267

页数：9