THEORETICAL-STUDY OF DOUBLY CHARGED NEGATIVE-IONS OF ELEMENTAL CLUSTERS - STABILITY OF C-8(2-)

被引:17
作者
ADAMOWICZ, L
机构
[1] Department of Chemistry, University of Arizona, Tucson, 85721, AZ
关键词
D O I
10.1063/1.461250
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A study was conducted for theoretical investigation of stability of doubly charged negative ions of elemental clusters, such as C2-8. The study demonstrated that the C2-8 system was stable with respect to electron detachments in agreement with the experimental observation. The investigations showed the final total energies and the first and second vertical electron affinities of C8. Both second electron affinities were positive, indicating that the C2-8 anion should be stable and long lived.
引用
收藏
页码:8669 / 8670
页数:2
相关论文
共 16 条
[11]   THEORETICAL VIBRATIONS OF CARBON CHAIN-C3, CHAIN-C4, CHAIN-C5, CHAIN-C6, CHAIN-C7, CHAIN-C8, AND CHAIN-C9 [J].
KURTZ, J ;
ADAMOWICZ, L .
ASTROPHYSICAL JOURNAL, 1991, 370 (02) :784-790
[12]  
REDMON LT, 1979, J AM CHEM SOC, V101, P2865
[13]   PRODUCTION OF SMALL DOUBLY CHARGED NEGATIVE CARBON CLUSTER IONS BY SPUTTERING [J].
SCHAUER, SN ;
WILLIAMS, P ;
COMPTON, RN .
PHYSICAL REVIEW LETTERS, 1990, 65 (05) :625-628
[14]   TOWARDS A FULL CCSDT MODEL FOR ELECTRON CORRELATION [J].
URBAN, M ;
NOGA, J ;
COLE, SJ ;
BARTLETT, RJ .
JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (08) :4041-4046
[15]   CARBON MOLECULES, IONS, AND CLUSTERS [J].
WELTNER, W ;
VANZEE, RJ .
CHEMICAL REVIEWS, 1989, 89 (08) :1713-1747
[16]   UPS OF 2-30-ATOM CARBON CLUSTERS - CHAINS AND RINGS [J].
YANG, S ;
TAYLOR, KJ ;
CRAYCRAFT, MJ ;
CONCEICAO, J ;
PETTIETTE, CL ;
CHESHNOVSKY, O ;
SMALLEY, RE .
CHEMICAL PHYSICS LETTERS, 1988, 144 (5-6) :431-436